Sulfates in Shampoo: Are They Bad for Your Hair?

Sulfates in Shampoo: Are They Bad for Your Hair?

By Hairstory

Published on September 27, 2024 — 4 min read

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The field of skin surface lipids (“lipidomics”) is constantly evolving and is open for many new discoveries. But here’s what we know so far: In nature, layers of waxes act as protection for leaves and fruits of plants, or skin, feathers, and fur of animals. Waxes are resistant to oxidation, water, and heat. Besides protection, they also serve as lubrication.

Additionally, they seal in the internal moisture of tissues while preventing excessive hydration. In certain instances, wax crystals demonstrate unusual surface self-cleaning properties that repel not only moisture but also physical or biological invaders. And here’s what we know about sulfates: sulfate-based shampoos and soaps are too-effective cleansers that destroy these essential, waxy layers and leave our skin and hair vulnerable.

SULFATES AND CLEANSING

Shampoo has been part of our lives, our parents’ lives, grandparents, great-grandparents, great-great-great grandparents’ lives (you get the point), but what do we really know about this sudsy stuff? We know that sulfates are responsible for creating the lather in shampoos and soaps, and for removing dirt and oil.

Sulfates are considered safe in concentrations below 1 percent or when used for short periods of time, according to the Journal of the American College of Toxicology, although any concentration over 2 percent will cause some degree of skin irritation. But, a shampoo that contains sulfates typically has a concentration of around 15 percent, and is packed with conditioning agents to buffer the drying effects.

 

There are more than 100 different varieties of sulfates – some synthetic, others made from natural sources, like coconut or palm oils. Some are derived from sulfur- and petroleum-based products. If your shampoo foams, it contains some form of sulfate. And with sulfates now on the least-wanted list, lather may be a thing of the past. Say hello to “squeakless-clean.”

Find a more detailed explanation of the science and safety of sulfates here.

SULFATES AND HAIR

Hair is made of about 91 percent protein. When that protein is damaged, it can weaken, break, split, and misbehave. Sulfates are closely linked with such damage. One study from 2005 shows that hair immersed in a sodium dodecyl sulfate solution loses seven times as much protein as hair immersed in water. If your hair is very fine, losing a little protein can add up to a big problem.


SULFATES AND SKIN

Sulfates can cause severe skin irritation and a painful or itchy rash called contact dermatitis. People with low levels of ceramides – one type of waxy lipid found in skin cells – are more likely to experience dermatitis after being exposed to sulfates. By the time you reach your early 30s, the level of ceramides in your skin begins to decrease, your skin barrier weakens, which on its own can lead to irritation, dryness, and redness. Best not to add injury (sulfates) to insult (aging).


SULFATE-FREEDOM

Sulfate-free shampoos feel different. There’s less foaming, they require some extra rinsing, and the “squeaky-clean” feel we’ve been taught to love doesn’t hold water after all. Hairstory offers three versions of its signature product called New Wash, a pioneer in the category that is not only sulfate-free but entirely detergent-free.

Below the hairline is the province of the people at the Crude product company who sum it up this way: “Sudsing cleansers have only been the norm in human hygiene for the last century – before the industrial revolution, humans cleansed primarily with natural ingredients like water, oil, and clay.” It seems like the time for another revolution.

Frequently Asked Questions

  • What are sulfates and why are they used in shampoo?
    Sulfates are the compounds responsible for creating lather in shampoos and soaps and for removing dirt and oil. There are more than 100 different varieties—some synthetic, others derived from natural sources like coconut or palm oils, and some from sulfur- and petroleum-based products. If your shampoo foams, it contains some form of sulfate.
  • Are sulfates safe to use in shampoo?
    Sulfates are considered safe in concentrations below 1 percent or when used for short periods of time, according to the Journal of the American College of Toxicology. However, any concentration over 2 percent will cause some degree of skin irritation—and most sulfate-containing shampoos have concentrations around 15 percent, far above that threshold.
  • How do sulfates damage hair?
    Hair is made of about 91 percent protein, and when that protein is damaged, hair can weaken, break, split, and misbehave. A 2005 study found that hair immersed in a sodium dodecyl sulfate solution loses seven times as much protein as hair immersed in water alone. For people with fine hair, even modest protein loss can add up to a significant problem.
  • Can sulfates cause skin irritation or rashes?
    Yes—sulfates can cause severe skin irritation and a painful or itchy rash called contact dermatitis. People with low levels of ceramides, a type of waxy lipid found in skin cells, are especially susceptible. Ceramide levels naturally begin to decline in the early 30s, weakening the skin barrier and making sulfate exposure even more problematic.
  • What are skin surface lipids and why do they matter?
    Skin surface lipids—including waxes—form a protective layer on skin, hair, feathers, and fur. These layers resist oxidation, water, and heat; seal in internal moisture; prevent excessive hydration; and can even repel physical or biological invaders. Sulfate-based shampoos and soaps strip away these essential protective layers, leaving skin and hair vulnerable.
  • What is a detergent-free alternative to sulfate shampoo?
    Hairstory's New Wash is a detergent-free cleansing cream that replaces both shampoo and conditioner without stripping the scalp's natural protective lipid layers. It comes in three formulas—New Wash (Original), New Wash (Rich), and New Wash (Deep)—designed for different hair types, from normal and thick to dry and coarse to fine and oily.
  • Does sulfate-free hair cleanser feel like regular shampoo?
    Sulfate-free cleansers feel different from conventional shampoos—there is less foaming, they require some extra rinsing, and the familiar 'squeaky-clean' sensation is absent. That squeaky feeling is actually a sign that protective oils and lipids have been stripped from the hair and scalp, not a mark of ideal cleanliness.

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